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BRIDGED AROMATIC COMPOUNDSPDF|Epub|txt|kindle电子书版本网盘下载
- 著
- 出版社: ACADEMIC PRESS
- ISBN:
- 出版时间:1964
- 标注页数:553页
- 文件大小:96MB
- 文件页数:565页
- 主题词:
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图书目录
NOMENCLATURE1
Polymethylene or Disubstituted Aromatic System2
Phenylene System3
Benzo system4
Ansa System5
Bicyclo System5
Cyclophane System6
A New System8
PREPARATION24
The Acyloin Cyclization Method27
The Friedel-Crafts Cyclization Method43
The Halo-Amine Cyclization Method66
The Halo-Ether Cyclization Method75
The wurtz Reaction88
The Ziegler Cyclization Method96
Cyclization by Pyrolysis of Acids and Their Salts100
Pyrolysis of Hydrocarbons105
The Hofmann Elimination Reaction Method106
Cyclization by Pyrolysis of Other Compounds112
The Ring-Contraction Method114
Cyclization by Oxidative Coupling115
Nonaromatic Routes to Bridged Aromatics121
The Depolymerization Cyclization Method131
The Dieckmann Cyclization Method133
Cyclization by Amide Formation136
Cyclization by Imine Formation142
Miscellaneous Methods of Preparing Cyclophanes147
Porphyrins and Related Compounds Containing Bridged Aromatic Nuclei176
Natural Products Containing Cyclophane Links178
References185
CHEMISTRY OF THE BRIDGED NUCLEUS201
Carbon-Hydrogen Substituents202
Halogen and Halogen-Containing Substituents208
Oxygen-Containing Substituents213
Nitrogen-Containing Substituents236
Sulfur-Containing Substituents244
Rearrangement of Cyclophane Bridges245
Hydrogenation of the Aromatic Nucleus247
Molecular Complexes of the Cyclophanes249
Inclusion Compounds of the Cyclophanes256
Photochemical Studies258
Dehydrogenation of Cyclophanes to Polycyclics259
Diels-Alder Reactions260
References262
CHEMISTRY OF THE BRIDGE267
Carbon-Hydrogen Substituents267
Oxygen-Containing Substituents282
Halogen Substituents316
Nitrogen and Sulfur Substituents320
Methylene Acidity324
Bridgehead Oxidations324
References326
DISSYMMETRY OF THE BRIDGED AROMATICS333
Text333
References357
ULTRAVIOLET ABSORPTION SPECTROSCOPY359
Text359
References382
INFRARED ABSORPTION SPECTROSCOPY385
Text385
References392
χ-RAY AND OTHER STRUCTURAL STUDIES393
Text393
References406
NUCLEAR AND ELECTRON MAGNETIC RESONANCE STUDIES407
Nuclear Magnetic Resonance407
Electron Paramagnetic Resonance419
References421
TABLES OF COMPOUNDS423
Tables424
References495
Author Index503
Subject Index525